Modeling of Synthesis of Aluminum Hydride via Binary Hydrides of Alkaline Earth Metals
DOI:
https://doi.org/10.6000/1929-5030.2018.07.02Keywords:
Hydride, aluminium, synthesis, programmed synthesis, autoinitiation.Abstract
In this article given the mathematical modeling of energy-intensive substances obtaining, which allows expanding the resource base, providing the possibility of using various binary hydrides in the process of aluminum hydride - AlH3 synthesis.
Due to the absence of soluble hydride forms of binary hydrides of alkaline-earth (MH2) metals, it is necessary to carry out at least 4-6 steps of the process for the production of aluminum hydride. Polynomials for the programmed synthesis of AlH3 with autoinitiation have been developed.
A programmed synthesis of aluminum hydride with autoinitiation was developed and implemented, which allows expanding the raw material base enabling the synthesis of other metal hydrides.
References
[1] Mirsaidov UM. Synthesis and properties of aluminum hydride. Dushanbe: Donish 2004; p. 105.
[2] Finholt AE, Bond AC Jr, Schlesinger HI. Journal of the American Chemical Society 1947; 69(5): 1199-1203.
[3] Bulychev BM, Verbetsky VN, Sizov AI, Zvukova TM, Fomin VN. Proceedings of the Academy of Sciences of the Russian Federation. Chemistry Series 2007; 7: 1259-1265.
[4] Bulychev BM, Verbetsky VN, Storozhenko PA. Journal of Inorganic Chemistry 2008; 52: 1081.
[5] Mirsaidov UM, Badalov A, Nasrulloyeva DH, Gafurov BA. Proceedings of the Academy of Sciences of the Republic of Tajikistan. Series of Sci Chem Geol and Tehn Sciences 2011; 3(144): 78-85.
[6] ?rower FM, Matzek NE, Reigler PF, Rinn HW, Roberts CB, Schmidt DL, Snover JA, Terada K. Preparation and Properties of Aluminum Hydride (Eng.). Journal of the American Chemical Society 1976; 98(9): 2450-2453.
[7] Mirsaidov UM, Badalov A, Dymova TN. Thermal stability and thermodynamic properties of aluminum hydride. Dushanbe: Donish 2017; p. 45.
[8] ?irsaidov U. Synthesis, properties and assimilation methods of aluminium hydride. Edited by T. Nejat Veziro?lu, Svetlana Yu Zaginaichenko, Dmitry V. Schur, Bogdan Baranowski, Anatoliy P. Shpak. Hydrogen Materials Science and Chemistry of Carbon Nanomaterials: NATO Science for Peace and Security Series. NATO Science for Peace and Security Series A: Springer 2007; p. 77-85.
[9] Patent 3801657 (USA). Direct crystallisation of aluminium hydride from the toluene-ether mixture. ?. James. Application 15.01.69 y., published 02.04.74 y. 1975, 5?66 ?.
[10] Patent 3810974 (USA). Synthesis of aluminium hydride. Application 05.05.64 y., published 14.05.74 y. 1975, 7?89 ?.
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