Electrodialytic Removal of Cadmium from Brackish Water: Effects of Operating Parameters
DOI:
https://doi.org/10.6000/1929-6037.2014.03.02.1Keywords:
Electrodialysis, Synthetic brackish water, Demineralization rate, Cadmium removal, Process efficiency.Abstract
The continuous increase of environmental regulations make interesting to find effective and efficient methods for processing effluents containing metal ions. This research focuses on cadmium removal from brackish water by an electro-membrane process: The electrodialysis. Experiments were carried out on synthetic brackish water solutions and using a laboratory scale electrodialysis system. The influence of several parameters on process efficiency was investigated. The efficiency of this process was assessed by the determination of five parameters: The demineralization rate, the removal rate and the transport flux of cadmium, the current efficiency and the specific power consumption. The applied voltage, the feed flow rate, the pH and cadmium initial concentration of the feed solution have a significant effect on the process efficiency and mainly on the cadmium transfer from dilute to concentrate compartment. In contrast, feed ionic strength seems to affect only the SPC and not the R(Cd).
References
World Health Organization. Cadmium in Drinking-water; 2011: Available from: http://www.who.int/water_sanitation_ health/dwq/chemicals/cadmium.pdf
World Health Organization. Guidelines for drinking-water quality.4th ed.; 2011: Available from: http://whqlibdoc.who.int/ publications/2011/9789241548151_eng.pdf
Naushad M, Al-Othman ZA, Islam M. Adsorption of cadmium ion using a new composite cation-exchanger polyaniline Sn(IV) silicate: kinetics, thermodynamic and isotherm studies. Int J Environ Sci Technol 2013; 10: 567-78. http://dx.doi.org/10.1007/s13762-013-0189-0 DOI: https://doi.org/10.1007/s13762-013-0189-0
Abdel Salam M. Removal of heavy metal ions from aqueous solutions with multi-walled carbon nanotubes: Kinetic and thermodynamic studies. Int J Environ Sci Technol 2012: 1-12. DOI: https://doi.org/10.1007/s13762-012-0127-6
Kumar R, Jain SK, Misra RK, Kachchwaha M, Khatri PK. Aqueous heavy metals removal by adsorption on β-diketone-functionalized styrene–divinylbenzene copolymeric resin. Int J Environ Sci Technol 2012; 9: 79-84. http://dx.doi.org/10.1007/s13762-011-0019-1 DOI: https://doi.org/10.1007/s13762-011-0019-1
Zamani AA, Shokri R, Yaftian MR, Parizanganeh AH. Adsorption of lead, zinc and cadmium ions from contaminated water onto Peganum harmala seeds as biosorbent. Int J Environ Sci Technol 2013; 10: 93-102. http://dx.doi.org/10.1007/s13762-012-0107-x DOI: https://doi.org/10.1007/s13762-012-0107-x
Ballet GT, Gzara L, Hafiane A, Dhahbi M. Transport coefficients and cadmium salt rejection in nanofiltration membrane. Desalination 2004; 167: 369-76. http://dx.doi.org/10.1016/j.desal.2004.06.148 DOI: https://doi.org/10.1016/j.desal.2004.06.148
Jellouli Ennigrou D, Gzara L, Ramzi Ben Romdhane M, Dhahbi M. Cadmium removal from aqueous solutions by polyelectrolyte enhanced ultrafiltration. Desalination 2009; 246: 363-9. http://dx.doi.org/10.1016/j.desal.2008.04.053 DOI: https://doi.org/10.1016/j.desal.2008.04.053
Lee G. Effects of operating parameters on the removal performance of electrodialysis for treating wastewater containing cadmium. Desalin Water Treat 2011; 35: 150-7. http://dx.doi.org/10.5004/dwt.2011.2850 DOI: https://doi.org/10.5004/dwt.2011.2850
Ghyselbrecht K, Huygebaert M, Van der Bruggen B, Ballet R, Meesschaert B, Pinoy L. Desalination of an industrial saline water with conventional and bipolar membrane electrodialysis. Desalination 2013; 318: 9-18. http://dx.doi.org/10.1016/j.desal.2013.03.020 DOI: https://doi.org/10.1016/j.desal.2013.03.020
Banasiak LJ, Schäfer AI. Removal of boron, fluoride and nitrate by electrodialysis in the presence of organic matter. J Memb Sci 2009; 334: 101-9. http://dx.doi.org/10.1016/j.memsci.2009.02.020 DOI: https://doi.org/10.1016/j.memsci.2009.02.020
Moon SH, Yun SH. Process integration of electrodialysis for a cleaner environment. Curr Opin Chem Eng 2014; 4: 25-31. http://dx.doi.org/10.1016/j.coche.2014.01.001 DOI: https://doi.org/10.1016/j.coche.2014.01.001
Ben Sik Ali M, Mnif A, Hamrouni B, Dhahbi M. Electrodialytic desalination of brackish water: Effect of process parameters and water characteristics. Ionics 2010; 16: 621-9. http://dx.doi.org/10.1007/s11581-010-0441-2 DOI: https://doi.org/10.1007/s11581-010-0441-2
Baker RW. Membrane technology and applications. 2nd ed. John Wiley & Sons: England 2004. http://dx.doi.org/10.1002/0470020393 DOI: https://doi.org/10.1002/0470020393
Noble RD, Stern SA. Membrane separations technologies Principles and Applications.Elsevier Science: Amsterdam 1995.
Strathmann H. Electrodialysis, a mature technology with a multitude of new applications. Desalination 2010; 264: 268-88. http://dx.doi.org/10.1016/j.desal.2010.04.069 DOI: https://doi.org/10.1016/j.desal.2010.04.069
Casademont C, Farias MA, Pourcelly G, Bazinet L. Impact of electrodialytic parameters on cation migration kinetics and fouling nature of ion-exchange membranes during treatment of solutions with different magnesium/calcium ratios. J Memb Sci 2008; 325: 570-9. http://dx.doi.org/10.1016/j.memsci.2008.08.023 DOI: https://doi.org/10.1016/j.memsci.2008.08.023
Wang Q, Ying T, Jiang T, Yang D, Jahangir MM. Demineralization of soybean oligosaccharides extract from sweet slurry by conventional electrodialysis. J Food Eng 2009; 95: 410-5. http://dx.doi.org/10.1016/j.jfoodeng.2009.05.024 DOI: https://doi.org/10.1016/j.jfoodeng.2009.05.024
Ergun E, Tor A, Cengeloglu Y, Kocak I. Electrodialytic removal of fluoride from water: Effects of process parameters and accompanying anions. Sep Purif Technol 2008; 64: 147-53. http://dx.doi.org/10.1016/j.seppur.2008.09.009 DOI: https://doi.org/10.1016/j.seppur.2008.09.009
Lambert J, Avila-Rodriguez M, Durand G, Rakib M. Separation of sodium ions from trivalent chromium by electrodialysis using monovalent cation selective membranes. J Memb Sci 2006; 280: 219-25. http://dx.doi.org/10.1016/j.memsci.2006.01.021 DOI: https://doi.org/10.1016/j.memsci.2006.01.021
Sadrzadeh M, Razmi A, Mohammadi T. Separation of different ions from wastewater at various operating conditions using electrodialysis. Sep Purif Technol 2007; 54: 147-56. http://dx.doi.org/10.1016/j.seppur.2006.08.023 DOI: https://doi.org/10.1016/j.seppur.2006.08.023
Ben Sik Ali M, Jellouli Ennigrou D, Hamrouni B. Iron removal from brackish water by electrodialysis. Environ Technol 2013: 1-28. DOI: https://doi.org/10.1080/09593330.2013.777081
Ben Sik Ali M, Hamrouni B, Dhahbi M. Electrodialytic defluoridation of brackish water: effect of process parameters and water characteristics. CLEAN – Soil, Air, Water 2010; 38: 623-9. DOI: https://doi.org/10.1002/clen.200900301
Puigdomenech I. Medusa Software. KTH Royal Institute of Technology, Department of Chemistry. Sweden; 2010 [cited 2010Dec06]: Available from: http://www.kth.se/en/che/ medusa/chemeq-1.369367
Downloads
Published
How to Cite
Issue
Section
License
Policy for Journals/Articles with Open Access
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work
Policy for Journals / Manuscript with Paid Access
Authors who publish with this journal agree to the following terms:
- Publisher retain copyright .
- Authors are permitted and encouraged to post links to their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work .