Membrane Stabilitiy and Removal of Cobalt from Waste Solution Using Liquid Emulsion Membrane
DOI:
https://doi.org/10.6000/1929-6037.2013.02.01.10Keywords:
Emulsion membrane, Cobalt Extraction, membrane StabilityAbstract
A Liquid Emulsion Mmenrane (LEM) containing Cyanex 301 as a carrier and Span 80 as a surfactant was used for the extraction of Co-(II) from nitric acid solution. Various diluents were tested and cyclohexane was found the most effective diluent in the cobalt extraction. The effect of different factors affecting the permeation of cobalt through LEM (e.g pH of the extrenal phase, type and concentration of stripping internal phase, the equilibrium time, and Cyanex 301 conentration) were investigated. The effects of surfactant types and cocentrations on the stbility of LEM were also studied. It was found that the optimum conditions for cobalt extraction using 8% Cyanex 301 were as follows; 3M HCl as an internal phase, 4% span 80 as a surfactant and by using the best conditions 10 ml of prepared LEM can extract about 96.86% of 1 gm/l of cobalt in Nitric acid solution after 5 min. in the reactor tank.
References
Forsythe JHW, Magee RJ, Wilson CL. The analytical chemistry of the pyridine thiocyanates-I: The separation of cobalt and nickel by solvent extraction. Talanta 1958; (1): 249-51. http://dx.doi.org/10.1016/0039-9140(58)80041-7 DOI: https://doi.org/10.1016/0039-9140(58)80041-7
Li NN. Separating hydrocarbons with liquid membranes US Patent 3,410,794, 1968.
Cahn RP, Li NN. New Development in Separation Methods. Marcel Dekker Inc., New York 1976; pp. 13-27.
Park Y, Skell AHP, Forney LJ, Kim JH. Removal of Phenol and Substituted Phenols by Newly Developed Emulsion Liquid Membrane Process. Water Res 2006; (40): 1763-72. http://dx.doi.org/10.1016/j.watres.2006.03.005 DOI: https://doi.org/10.1016/j.watres.2006.03.005
Luan J, Plaisicr A. Study on treatment of wastewater containing nitrophenol compounds by liquid membrane process. J Membr Sci 2004; (229): 235-39. http://dx.doi.org/10.1016/j.memsci.2003.08.019 DOI: https://doi.org/10.1016/j.memsci.2003.08.019
Chakraborty M, Bart HJ. Emulsion liquid membranes: Role of internal droplet size distribution on toluene/n-heptane separation. Colloids Surfaces A: Physicochemical and Engineering Aspects 2006; (272): 15-21. http://dx.doi.org/10.1016/j.colsurfa.2005.07.002 DOI: https://doi.org/10.1016/j.colsurfa.2005.07.002
Boyadzhiev L, Lazarova Z. Study on creeping film pertraction. Recovery of copper from diluted aqueous solutions. Chem Eng Sci 1987; 42(5): 1131-35. http://dx.doi.org/10.1016/0009-2509(87)80062-3 DOI: https://doi.org/10.1016/0009-2509(87)80062-3
Raghuraman B, Tirmizi N, Wiencek J. Extraction with emulsion liquid membranes in a hollow fiber contactor. AIChE J 1993; (39): 39-46. DOI: https://doi.org/10.1002/aic.690391115
Raghuraman B, Tirmizi N, Wiencek J. Emulsion liquid membranes for wastewater treatment: equipment models for some typical metal-extraction systems. Environ Sci Technol 1994; (28): 1090-102. http://dx.doi.org/10.1021/es00055a018 DOI: https://doi.org/10.1021/es00055a018
Kasaini H, Nakashio F, Goto M, Application of emulsion liquid membranes to recover cobalt ions from a dual-component sulphate solution containing nickel ions. J Membr Sci 1998; (146): 159-68. http://dx.doi.org/10.1016/S0376-7388(98)00105-7 DOI: https://doi.org/10.1016/S0376-7388(98)00105-7
Uddin MS, Kathiresan M. Extraction of metal ions by emulsion liquid membrane using bi-functional surfactant: equilibrium and kinetic studies. Sepa Purif Tech 2000; (19): 3-9. DOI: https://doi.org/10.1016/S1383-5866(99)00079-9
Chakravarti AK, Chowdhury SB, Mukherjee DC. Liquid membrane multiple emulsion process of separation of copper (II) form waste waters. Colloids and Surfaces a: Physiochemical and Engineering Aspects 2000; 166(1): 7-25. http://dx.doi.org/10.1016/S0927-7757(99)00452-5 DOI: https://doi.org/10.1016/S0927-7757(99)00452-5
Saravanan S, Begum KMMS, Anantharaman N. Removal of hexavalent chromium by emulsion liquid membrane technique. J Univ Chem Technol Metallur 2006; 41(3): 333-42.
Valenzuela F, Araneda C, Vargas F, Basualto C, Sapag J. Liquid membrane emulsion process for the recovery the copper content of a mine drainage 2009.
Chemical Engineering Research and Design, 87(1): 102-108. http://dx.doi.org/10.1016/j.cherd.2008.05.010 DOI: https://doi.org/10.1016/j.cherd.2008.05.010
Bhuvaneswari S, Begum KMMS, Sivashanmugam P, Anantharaman N. Separation of L-Glutamic acid by liquid emulsion membrane extraction. J Scient Ind Res 2003; (62): 329-33.
Venkatesan S, Begum KMMS, Sivashanmugam P, Anantharaman N. Extraction of L-Glutamic acid by liquid emulsion membrane. J Indian Chem Soc 2004; (81): 1-3.
Li NN. Liquid membrane processes for copper extraction. Hydrometallurgy 1983; (9): 277-305. http://dx.doi.org/10.1016/0304-386X(83)90027-0 DOI: https://doi.org/10.1016/0304-386X(83)90027-0
Sahoo GC, Dutta NN. Studies on emulsion liquid membrane extraction of cephalexin. J Membr Sci 1998; (145): 15-26. http://dx.doi.org/10.1016/S0376-7388(98)00027-1 DOI: https://doi.org/10.1016/S0376-7388(98)00027-1
Gurel L, Altas L, Buyukgungor H. Removal of Lead from Wastewater Using Emulsion Liquid Membrane Technique. Environ Eng Sci 2005; 22(4): 411-20. http://dx.doi.org/10.1089/ees.2005.22.411 DOI: https://doi.org/10.1089/ees.2005.22.411
Noviandri I. Thesis, Magister of Science, Bandung Institute of Technology, Indonesia 1992.
Kondo K, Matsumoto M, Separation and concentration of indium (III) by an emulsion liquid membrane containing diisostearylphosphoric acid as a mobile carrier. Separ Purif Tech 1998; (13): 109-15. http://dx.doi.org/10.1016/S1383-5866(97)00064-6 DOI: https://doi.org/10.1016/S1383-5866(97)00064-6
Ye ZF, Wang YP, Liu YS, Jiang ZI, Shen X, Zhu IG, Shi XF. Transport of Na+, K+ ions in a bubbling pseudo-emulsion liquid membrane system with p-tert-butylcalixarenes as carrier. J Membr Sci 1999; (163): 367-72. http://dx.doi.org/10.1016/S0376-7388(99)00180-5 DOI: https://doi.org/10.1016/S0376-7388(99)00180-5
Park WG, Kim SS, Sohn I. Facilitated transport of Cr (VI) through a supported liquid membrane with trioctylmethylammonium chloride as a carrier. J Sep Sci Technol 2001; 36(10): 2309-26. http://dx.doi.org/10.1081/SS-100105920 DOI: https://doi.org/10.1081/SS-100105920
Kozlowski CW, Apostoluk W, Walkowiak, Kita A. Removal of Cr (VI), Zn (II) and Cd (II) ions by transport across polymer inclusion membranes with basic ion carriers. Physiochem Probl Mineral Proc 2002; (36): 115-22.
Bourenane ME, Samar H, Abbaci A. Extraction of cobalt and lead from waste water using a liquid surfactant membrane emulsion. Acta Chim Slov 2003; (50): 663-75.
Basualto C, Poblete M, Marchese J, Ochoa A, Acosta A, Sapag J, Valenzuela F. Extraction of Cadmium from Aqueous Solutions by Emulsion Liquid Membranes using a Stirred Transfer Cell Contactor. J Braz Chem Soc 2006; 17(7): 1347-54. http://dx.doi.org/10.1590/S0103-50532006000700023 DOI: https://doi.org/10.1590/S0103-50532006000700023
Sabry R, Hafez A, Khedr M, Hassanin AE. Removal of lead by an emulsion liquid membrane: Part I. Desalination 2007; 212(1-3): 165-75. http://dx.doi.org/10.1016/j.desal.2006.11.006 DOI: https://doi.org/10.1016/j.desal.2006.11.006
Yang L, Zhang Z, Guo Y, Gao X, Takeuchi H. Uranium (VI) extraction by liquid surfactant membrane with N-alkylcaprolactams as a carrier. Separ Purif Tech 2005; (47): 88-94. http://dx.doi.org/10.1016/j.seppur.2005.06.007 DOI: https://doi.org/10.1016/j.seppur.2005.06.007
Kozlowski C, Walkowiak W. Applicability of liquid membranes in chromium (VI) transport with amines as ion carriers. J Membr Sci 2005; 266(1-2): 143-50. http://dx.doi.org/10.1016/j.memsci.2005.04.053 DOI: https://doi.org/10.1016/j.memsci.2005.04.053
Farhadi K, Shamsipur M, Separation Study of Cadmium as CdI42- through a Bulk Liquid Membrane Containing Ketoconazole and Oleic Acid. Anal Sci 2005; (21): 501-505. http://dx.doi.org/10.2116/analsci.21.501 DOI: https://doi.org/10.2116/analsci.21.501
Gawronski R, Religa P. Transport mechanism of chromium (III) through the unmixed bulk liquid membrane containing dinonylnaphthalenesulfonic acid as a carrier. J Membr Sci 2007; 289(1-2): 187-90. http://dx.doi.org/10.1016/j.memsci.2006.11.053 DOI: https://doi.org/10.1016/j.memsci.2006.11.053
Chiha M, Samar MH, Hamdaoui O. Extraction of chromium (VI) from sulphuric acid aqueous solutions by a liquid surfactant membrane (LSM). Desalination 2006; (194): 69-80. http://dx.doi.org/10.1016/j.desal.2005.10.025 DOI: https://doi.org/10.1016/j.desal.2005.10.025
Ribeiro CP, Costa AOS, Lopes IPB, Campos FF, Ferreira AA, Salum A. Cobalt extraction and cobalt-nickel separation from simulated industrial leaching liquor by liquid surfactant membranes using Cyanex 302 as carrier. Membr Sci 2004; (241): 45-54. DOI: https://doi.org/10.1016/j.memsci.2004.03.038
Thakul NV, Mishra SL. Separation of Cobalt, Nickel, and Copper by Solvent Extraction using di-(2-ethylhexyl) Phosphoric Acid, PC88A. Hydrometallurgy 1998; (48): 277. DOI: https://doi.org/10.1016/S0304-386X(97)00075-3
Longquan L, Cheng W, Yadong L, Separation of Cobalt and Nickel by Emulsion Liquid Membrane with the Use of EDTA as Masking Reagent. J Membr Sci 1997; (135): 173. DOI: https://doi.org/10.1016/S0376-7388(97)00178-6
Reddy BR, Radhika P, Kumar JR, Priya DN, Rajgopal K. Extractive spectrometric determination of Co(II) in synthetic and pharmaceutical samples using CYANEX 923. Anal Sci 2004; (20): 345-49. http://dx.doi.org/10.2116/analsci.20.345 DOI: https://doi.org/10.2116/analsci.20.345
Gupta B, Tandon SN, Deep A, Recovery of cobalt and nickel from spent catalysts using CYANEX 923, in: Proceedings of the International Solvent Extraction Conference, ISEC 2002; pp. 793-797.
Teramoto M, Sakaramoto T, Koyama T, Matsuyama H, Miyake Y. Extraction of lanthanoids by liquid surfactant memrannes. Sep Sci Technol 1986; 21(3): 229-50. http://dx.doi.org/10.1080/01496398608058375 DOI: https://doi.org/10.1080/01496398608058375
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