Effect of Hydroxyl-Terminated Random Copolyether (PET) and Hydroxyl-Terminated Polybutadiene (HTPB) on Thermal Decomposition Characteristics of Ammonium Perchlorate

Authors

  • Ke-Zhu Mao School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
  • Min Xia School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
  • Yun-Jun Luo School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

DOI:

https://doi.org/10.6000/1929-5995.2015.04.01.5

Keywords:

Insensitive propellant, TGA-FTIR, Thermal Decomposition characteristics, porous structure, N2O.

Abstract

The effects of two binders (PET and HTPB) on thermal decomposition characteristics of Ammonium Perchlorate were studied by TG-FTIR, DSC and SEM. When Hydroxyl-terminated polybutadiene (HTPB) mixes with AP, there is no obvious mutual effect in the process of heating, but it happen in the other way when Hydroxyl-terminated random copolyether (PET) mixes with AP. During the heating process of PET-AP mixture, the decomposition of PET occur in advance significantly, so that the porous structure of AP at the low-temperature decomposition stage becomes more significant, the total amount of heat released increases significantly, and the weight-loss ratio of AP about the two stages increases to about 2:1. During the thermal decomposition, the heat release and N2O gas production of PET-AP mixture is milder than the HTPB-AP, which is more conducive to the insensitive properties of propellant.

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Published

2015-04-17

How to Cite

Mao, K.-Z., Xia, M., & Luo, Y.-J. (2015). Effect of Hydroxyl-Terminated Random Copolyether (PET) and Hydroxyl-Terminated Polybutadiene (HTPB) on Thermal Decomposition Characteristics of Ammonium Perchlorate. Journal of Research Updates in Polymer Science, 4(1), 42–49. https://doi.org/10.6000/1929-5995.2015.04.01.5

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